## Abstract The photolysis of symmetric and asymmetric organomercury compounds has been studied by CIDNP. No indications of the existence of RHg· radicals have been found. Depending on the solvent, reactions occur from excited states with different spin multiplicities.
Dynamic nuclear polarisation of biological matter
✍ Scribed by H. B. Stuhrmann; O. Schärpf; M. Krumpolc; T. O. Niinikoski; M. Rieubland; A. Rijllart
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 464 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1432-1017
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✦ Synopsis
Polarised targets as used in high energy physics experiments may be of considerable interest in biological structure research using polarized neutrons. So far, this promising method has been facing difficulties in getting reasonable polarization of the target nuclei. We report on a polarized "frozen spin" target which has been prepared from an enzyme dissolved in a mixture of heavy water and deuterated propanediol doped with a completely deuterated paramagnetic radical. Clusters of 700 protons defined by the structure of lysozyme embedded in a fully deuterated matrix were polarized to 75% within an hour by 4 mm microwave irradiation in a magnetic field of 2.5 tesla at a temperature of 0.3 K. The polarisation behaviour of biological targets can be compared to the best frozen spin target materials in high energy physics research.
📜 SIMILAR VOLUMES
We calculate the equation of state of isospin-symmetric nuclear matter in the three-loop approximation of chiral perturbation theory. The contributions to the energy per particle E(k f ) from one-and two-pion exchange diagrams are ordered in powers of the Fermi momentum k f (modulo functions of k f
An equation of state (EOS) of nuclear matter with explicit inclusion of a spin-isospin dependent force is constructed from a finite range, momentum and density dependent effective interaction. This EOS is found to be in good agreement with those obtained from more sophisticated models for unpolarise