✦ LIBER ✦
Dynamic NMR study of chair–chair interconversion in N,N -dimethylpiperidinium iodide in aqueous solution using 13C T1p measurements
✍ Scribed by David M. Doddrell; Peter F. Barron; James Field
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 186 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^13^C T~1ρ~ values measured for N,N‐dimethylpiperidinium iodide yield activation parameters (Δ__H__^≠^ and Δ__G__ values of 43.7 and 41.6 kJ mol^−1^) for the chair‐chair interconversion in aqueous solution similar to those measured for 1,1‐dimethylcyclohexane. The potential of ^13^C T~1ρ~ values for studying dynamic processes in aqueous solutions is illustrated.