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Dynamic Monte-Carlo simulation of electrochemical switching of a conducting polymer film

โœ Scribed by Kourosh Malek


Book ID
104108228
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
390 KB
Volume
375
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Dynamic Monte-Carlo simulations of insulating/conducting transition of an electrochemically deposited conductive polymer film have shown that the peak potential of linear sweep voltammetry could be considered as a first approximation of the percolation threshold potential of the deposited film. In order to verify this, the insulating/conducting transition of the electrochemically deposited poly-ortho-aminophenol (POAP) films was studied by chronoamperometry. The propagating conductive clusters in the film were found to percolate at the threshold potential in the range of 0.15-0.17 V/Ag, AgCl, near the peak potential of the corresponding cyclic voltammogram.


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