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Dynamic molecular motions of guest molecule included in modified β-cyclodextrins

✍ Scribed by Iwao Tabushi; Yasuhisa Kuroda; Masahiko Yamada


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
271 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis


Upon inclusion in capped B-cyclodextrin, the overall reorientational motion of doubly deuterium labeled p-methylcinnamic acid slows down by a factor of 14 compared with that in an aqueous solution but the internal rotation of the methyl group still remains free.

In order to design sophisticated host molecules such as artificial receptors, it is important to understand the nature of "recognition"


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