Dynamic modeling of chemical reactions: the Diels-Alder cycloaddition
✍ Scribed by J. Weber; D. Mottier; P.-A. Carrupt; P. Vogel
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 301 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0263-7855
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract Under microwave conditions, o‐quinol dimers smoothly react with several olefins and acetylenes to afford bicyclooctenes with high diastereoselectivity.
The simple chemical modification by Diels ± Alder reactions of the cyclic hexamer of furan and acetone, utilising two readily accessible dienophiles, benzyne and dimethylacetylenedicarboxylate (DMAD), is described. The studies have explored the ease with which different furan units within the macroc