Dynamic mechanical behavior of a polyimide

✍ Scribed by G. A. Bernier; D. E. Kline

• Publisher: John Wiley and Sons
• Year: 1968
• Tongue: English
• Weight: 706 KB
• Volume: 12
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.1968.070120317

✦ Synopsis

The dynamic mechanical properties of a polyimide (poly-4,4 '-0xydiphenylene pyromellitimide) were studied from about 4 to 800°K. a t audio frequencies. A prominent relaxation associated with absorbed water content occurs near 230°K. Below 270°K., the modulus undergoes a corresponding increase in value with increasing water content. Above 550°K. the onset of a major relaxation process is observed in the modulus data, and a maximum in the internal friction is observed at about 675°K. Minor relaxation peaks are also noted throughout the temperature range. Relatively minor differences are noted in the mechanical relaxation spectra for the polyimide when treated (after drying) with dimethylformamide, dimethylacetamide, and dimethylsulfoxide, whereas the treatment with water after drying has a marked effect on the relaxation behavior.

A reactor radiation dose of 3000 Mrad also causes only minor alterations in the dynamic mechanical spectra.