✦ LIBER ✦

Dynamic kinetic resolution of hemiaminals with axially chiral twisted amides

✍ Scribed by Shinji Yamada; Emiko Noguchi

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 84 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00521-4

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✦ Synopsis

Dynamic kinetic resolution of N-acylhemiaminals was performed by enantioselective acylation of the hydroxy groups with chiral twisted amides. The stereoselectivity was reversed in the presence of 4-DMAP. The absolute configuration of the products was determined based on the sign of CD Cotton effects.

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