The EPR spectra of X-ray-irradiated single crystals of NaCl and KC1 doped with cyanide complexes of Pd have been studied at 77 K. The measured g and A values indicate the formation of [ Pd( CN),C12] "-(n= 3, 5 ) complexes. Ligand field parameters and spin densities have been estimated for the oxidiz
Dynamic effects in Ni (III) and Pd (III) cyanides in KCl and NaCl studied by EPR spectroscopy
✍ Scribed by N.V. Vugman; M.L. Netto Grillo; V.K. Jain
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 235 KB
- Volume
- 188
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The temperature dependence of the spin Hamiltonian parameters for the trivalent nickel and palladium tetracyanides in KCI and NaCI host lattices have been measured by electron paramagnetic resonance spectroscopy in the range 12-300 K and attributed to the effect of localized anharmonic vibration modes. A recently published theory is used to interpret the experimental data.
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