Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR
β Scribed by Sergei G. Sakharov
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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The preparation and characterization of Rh I , Pd II , and Pt II through conformational equilibration of the chelate ring, and/or inversion of configuration at the stereogenic sulfur. In complexes with chiral C 2 -symmetrical dithioether ligands derived from 1,1Π-binaphthalene-2,2Π-dithiol (BINAS) a
## Abstract The two macrocyclic hexathioethers, 1,4,7,12,15,18βhexathiacyclodocosane (22S6) and 1,4,7,11,14,17βhexathiacycloeicosane (20S6) have been examined with respect to their complexation behavior towards a variety of transition metals ions. In all of these complexes, the two ligands generate