## Abstract Based on previous works, a simple model is built to simulate the vinyl chloride monomer (VCM) polymerization in continuous suspension and bulk reactors. The branches of steadyβstate solutions are computed and their dynamic behavior is analyzed. It is observed that these systems present
Dynamic behavior of continuous vinyl chloride suspension polymerization reactors: Effects of segregation
β Scribed by J. C. Pinto
- Publisher
- Society for Plastic Engineers
- Year
- 1990
- Tongue
- English
- Weight
- 517 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0032-3888
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
Assumed is that there is no mass transfer among the droplets of reacting organic phase in a continuous vinyl chloride (VCM) suspension polymerization reactor. A mathematical model is thus developed to allow the calculation of steady states and the analysis of their dynamic stability. The results obtained are compared with those obtained with the hypothesis of perfect micromixing. It Is shown that both assumptions lead to similar dynamic structures, which confirms the complex behavior of these reactors. There are major differences, however, that can be exploited in future experimental work.
π SIMILAR VOLUMES
The effects of some polymerization conditions on poly(vinyl chloride) (PVC) particles produced by the suspension polymerization process were studied on a laboratory scale. The different stages of vinyl chloride suspension polymerization were investigated experimentally by using an on-line sample wit
Industrial autothermal cationic isobutylene polymerization reactors may present very complex dynamic behavior and difficult operation. A mathemathical model was developed to describe the operation of an autothermal solution industrial reactor, and some possible sources of complex dynamical behavior
## SYNOPSIS A series of suspension polymerizations of vinyl chloride monomer (VCM) was carried out in a 5-L pilot plant reactor over the temperature range, 40-70Β°C. The reactor pressure and monomer conversion were monitored simultaneously every 7-8 min. The critical conversion X,, at which the liq