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Dynamic 13C NMR study of the cyclohexane ring in spirocyclohexanes

✍ Scribed by Pierre Iratçabal; Marie-Florence Grenier-Loustalot; Albert Lichanot; Franck Metras

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
306 KB
Volume
14
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

A dynamic study of spirocyclohexanes was carried out using low‐temperature ^13^C nuclear magnetic resonance spectroscopy. The variations of the energy barrier to inversion of the cyclohexane ring are interpreted in terms of the electronegativity of the heteroatoms of the spiro substituent.

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