✦ LIBER ✦

Dye laser photoacoustic overtone spectroscopy of CHBr3

✍ Scribed by Carlos Manzanares I; N.L.S. Yamasaki; Eric Weitz

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 403 KB
Volume: 144
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87086-6

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✦ Synopsis

Spectra of the v= 5 and v= 6. levels of the C-H stretch in CHBr, have been recorded via in-cavity dye laser photoacoustic spectroscopy. Linewidths for these absorptions have been determined and are discussed in light of existing theory and results on the linewidths of the corresponding transitions in CHCI,. When data on the fundamental are combined with v= 5 and v= 6 data it is possible to determine values for the local mode harmonic frequency and anharmonicity. Absolute absorption cross sections for the v= 5 and a= 6 levels are reported.

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