Two types of dual-phase polymer electrolytes (DPE), mixed latex DPE and core-shell latex DPE, were fabricated from styrene-butadiene rubber (SBR) and acrylonitrile-butadiene rubber (NBR) latex mixture, and from polybutadiene (PB)/ poly (vinyl pyrrohdone) (PVP) core-shell latex. Polar phases of films
Dual-phase polymer electrolyte with enhanced mechanical strength
β Scribed by Yukitoshi Takeshita; Toshihiro Ichino; Shiro Nishi
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 123 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
The effect of the heat treatment on the tensile properties and the dynamic moduli of polymer matrix films and polymer electrolytes were studied to further increase the mechanical properties. The crosslinking of latex particles brought about their improvements by heating. We have fabricated the polymer electrolyte with a tensile strength of 3.0 MPa, together with a conductivity above 1 mS/cm for application to a lithium secondary battery. This polymer electrolyte had the highest tensile strength among the known gel polymer electrolytes having conductivity over 1 mS/cm, although mechanical properties of plasticized polymer electrolytes have rarely been reported.
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A new type of dual-phase polymer electrolyte (DPE) film was prepared by mechanical mixing of a poly(epichlorohydrin-co-oxirane) (ECO) and poly(acrylonitrileco-butadiene) rubber (NBR) binary solution and then by solution casting. Both of the polymers are commercially available. The casting films were