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Dual Nucleophilic Substitution Reactions of O,O-Diethyl 2,4-dinitrophenyl Phosphate and Thionophosphate Triesters

✍ Scribed by Aguayo, Raul; Arias, Felipe; Cañete, Alvaro; Zuñiga, Carolina; Castro, Enrique A.; Pavez, Paulina; Santos, José G.


Book ID
118763604
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
289 KB
Volume
45
Category
Article
ISSN
0538-8066

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Nucleophilic substitution reactions of d
✍ Enrique A. Castro; Daniela Ugarte; M. Fernanda Rojas; Paulina Pavez; José G. San 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 200 KB

## Abstract The reactions of diethyl 4‐nitrophenyl phosphate (**1**) with a series of nucleophiles: phenoxides, secondary alicyclic (SA) amines, and pyridines are subjected to a kinetic study. Under excess of nucleophile, all the reactions obey pseudo‐first‐order kinetics and are first order in the