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Dual fluorescence of 4,4'-dimethylamino- and 4,4'-diaminophenyl sulfone. Consequences of d-orbital participation in the intramolecular charge separation process

✍ Scribed by Rettig, Wolfgang; Chandross, Edwin A.


Book ID
125837752
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
932 KB
Volume
107
Category
Article
ISSN
0002-7863

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Dual fluorescence of 4,4β€²-bis(dimethylam
✍ Lian C.T. Shoute πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 410 KB

4,4'-bis (dimethylamino) benzophenone (BDMABP) emits dual fluorescence. The dipole-moment change determined from the solvatochromic shift is 4.0 D in alcohols and 10.4 D in polar aprotic solvents. Both short and long wavelength fluorescence is observed in I-PrOH: DMSO mixed solvents. The Stokes shif