Dual-beam difference spectroelectrochemistry

✍ Scribed by C.William Anderson; Michael R. Cushman; S.Mark Kennedy; Julia R. Wheeler

• Book ID: 102627467
• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 381 KB
• Volume: 127
• Category: Article
• ISSN: 0003-2697
• DOI: 10.1016/0003-2697(82)90195-6

✦ Synopsis

An optically transparent thin-layer electrode with carbon fibers as the working electrode is described for use in dual-beam difference spectroscopy. This cell simplifies obtaining the spectrum of a species of interest in the presence of mediators, cofactors, etc. The spectroelectrochemistry of cytochrome c with a large excess of spectrally interfering mediator present is shown.