DRIVING FORCE OF THE HOMOALLYLIC REARRANGEMENT IN ACETOLYSIS OF exo-DEHYDRONORBORNYL p-BROMOBENZENESULFONATE 1
β Scribed by Winstein, S.; Walborsky, H. M.; Schreiber, Kurt
- Book ID
- 126301645
- Publisher
- American Chemical Society
- Year
- 1950
- Tongue
- English
- Weight
- 135 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
In the preceding letter we have reported on the apparently complex solvolyses of the norbornen-2-yl brosylates 1 and 2. In order to understand nore about the behaviour of hawallylic systems we have studied the acetolysis of the title cca-qzounds 2 and 4. In principle, both pair: of substrates (l/3 a
## Abstract The buffered trifluoroethanolyses and acetolyses of __exo__β(2βD)β **(6)** and __endo__β(2βD)β5βnorbornenβ2βyl brosylates **(7)** yielded __exo__β5βnorbornenβ2βyl and 3βnortricyclyl derivatives. The deuterium distribution in these products was determined unambiguously by ^2^HβNMR. and M