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Dressed potential energy surface of the hydrogen molecule in high-frequency Floquet theory

✍ Scribed by C. Pérez Del Valle; R. Lefebvre; O. Atabek

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
199 KB
Volume
70
Category
Article
ISSN
0020-7608

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✦ Synopsis

The potential energy surface resulting from the application of the high-frequency Floquet theory to the hydrogen molecule coupled to a linearly polarized field is determined. The method uses a standard quantum chemistry program. It is found that the anisotropy of the surface is more pronounced than in the case of the hydrogen molecular cation. This is indicative of a strong propensity for an alignment of the internuclear axis in the direction of the applied field.

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