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Doubly [SiMe2]-bridged Cs- and C2v-symmetric zirconocene catalysts for propylene polymerization. Synthesis and polymerization characteristics

✍ Scribed by Shigenobu Miyake; John E. Bercaw

Publisher: Elsevier Science
Year: 1998
Tongue: English
Weight: 307 KB
Volume: 128
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(97)00160-x

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## Abstract The acid‐catalyzed reaction between formaldehyde and 1__H__‐indene, 3‐alkyl‐ and 3‐aryl‐1__H__‐indenes, and six‐membered‐ring substituted 1__H__‐indenes, with the 1__H__‐indene/CH~2~O ratio of 2 : 1, at temperatures above 60° in hydrocarbon solvents, yields 2,2′‐methylenebis[1__H__‐inde