Doubly Metalated Thiobenzyl Alcohol—Thiobenzaldehyde Dianion

Doubly Metalated 2-Propene-1-thiol: Thio

Doubly Metalated 2-Propene-1-thiol: Thioacrolein Dianion

✍ Dipl.-Chem. Karlheinz Geiss; Bernhard Seuring; Reimund Pieter; Prof. Dr. Dieter 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 English ⚖ 219 KB

Bonding and Redox Properties of [Os3(CO)

Bonding and Redox Properties of [Os3(CO)9(tmbp)(L)] (tmbp=4,4′,5,5′-tetramethyl-2,2′-biphosphinine; L=CO, PPh3) Clusters with an Unprecedented Electron-Deficient Metallic Core and Doubly Bridging Biphosphinine Dianion

✍ Maarten J. Bakker; Frank W. Vergeer; František Hartl; Patrick Rosa; Louis Ricard 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB

Herein we describe in detail the bonding properties and electrochemical behavior of the first known triosmium carbonyl clusters with a coordinated redox-active ligand 4,4',5,5'-tetramethyl-2,2'-biphosphinine (tmbp), the phosphorus derivative of 2,2'-bipyridine. The clusters investigated were [Os 3 -