Double Salts in the SystemsMe+X–Me2+X2–H2O(Me+=K, NH4, Rb, Cs;Me2+=Mn, Co, Ni;X−=Cl, Br)
✍ Scribed by St Tepavitcharova; Chr Balarew; Chr Tzvetkova; Ol Angelova
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 182 KB
- Volume
- 143
- Category
- Article
- ISSN
- 0022-4596
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✦ Synopsis
The solubility diagrams of the systems CsBr-Me 2؉ Br 2 -H 2 O (Me 2؉ ؍ Mn, Co, Ni) and NH 4 Br-MnBr 2 -H 2 O have been determined at 25°C. Four previously unreported double salts, 2NH 4 Br ) MnBr 2 • 2H 2 O (space group P4 2 /mnm, a ؍ 7.886(1) A s ,
📜 SIMILAR VOLUMES
## Abstract A series of unusual dinuclear μ~2~‐(η^2^‐__NO__)‐nitrosoaniline‐bridged complexes [{(CO)~3~Re(μ‐X)}~2~ONC~6~H~4~NR~2~] (X = Cl, Br, I; R = Me, Et) with dichroic properties have been synthesised by reaction of pentacarbonylhalogenorhenium(I) [(CO)~5~ReX] (X = Cl, Br, I) with the correspo
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.