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Double Salt Formation in the Cu(HCOO)2–Sr(HCOO)2–H2O System

✍ Scribed by Dr. Violeta Vassileva

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
237 KB
Volume
30
Category
Article
ISSN
0232-1300

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✦ Synopsis

Double Salt Formation in the Cu(HCOO), -Sr(HCOO), -H,O System The solubility in the CU(HCOO)~ -Sr(HCOO),-HzO system has been studied by the method of physico-chemical analysis at 25 and 50 "C. It has been established that two double salts are formed in the system: CuSr,(HCOO), 8 H,O at 25 "C and CuSr(HCOO), ' 4 H,O at 50 "C. The latter salt has not yet been described in the literature. It has been characterized by X-ray powder diffraction and DT and T G analysis. CuSr(HCOO), . 4 H,O crystallizes in the triclinic system with lattice parameters a = 12.376(6) A, b = 13.394(4) A, c = 11.508(6) b;, CL = 93.38(3)", = 94.01(3)", y = 75.04(3)". Dehydration proceeds in two stages.

📜 SIMILAR VOLUMES

On Solid Solution Formation in the Cu(HC
On Solid Solution Formation in the Cu(HCOO)2-Co(HCOO)2-H2O System
✍ D. Stoilova 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 285 KB

Solubility in the \(\mathrm{Cu}(\mathrm{HCOO})_{2}-\mathrm{Co}(\mathrm{HCOO})_{2}-\mathrm{H}_{2} \mathrm{O}\) system has been studied at 25 and \(50^{\circ} \mathrm{C}\). Three series of solid solutions are formed in the system at \(50^{\circ} \mathrm{C}\) : solid solutions having the \(\mathrm{Co}\