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Double nucleophilic addition reaction to α,β-unsaturated aldimines promoted by aluminum chloride and a limited amount of water

✍ Scribed by Makoto Shimizu; Toshiki Ogawa; Takafumi Nishi

Book ID: 104231082
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 64 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01021-8

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✦ Synopsis

In the presence of AlCl 3 and MS 4 A containing H 2 O, ketene silyl acetals underwent 1,4-and then 1,2-addition with a,b-unsaturated imines to give doubly alkylated products in good yields with high diastereomeric excesses.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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