Double hydrogen atom transfer in lactamide radical cations via ion-neutral complexes

Intermediacy of Proton-Bound Dimers and

Intermediacy of Proton-Bound Dimers and Ion/Dipole Complexes in the Unimolecular Decompositions of Dialkyl-Peroxide Radical Cations: Evidence for a coupled proton and hydrogen-atom transfer

✍ Christoph A. Schalley; Detlef Schröder; Helmut Schwarz 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 694 KB

## Abstract The unimolecular fragmentation reactions of the radical cations of diethyl, diisopropyl, dipropyl, isopropyl propyl, and di(__tert__‐butyl) peroxide have been investigated by mass spectrometric and isotopic labeling techniques. Two competing pathways for unimolecular decomposition in th