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Double-Chelation-Assisted Rh-Catalyzed Intermolecular Hydroacylation.

โœ Scribed by Masakazu Tanaka; Masanori Imai; Yoichiro Yamamoto; Keitaro Tanaka; Masato Shimowatari; Shinji Nagumo; Norio Kawahara; Hiroshi Suemune

Publisher
John Wiley and Sons
Year
2003
Weight
137 KB
Volume
34
Category
Article
ISSN
0931-7597

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The work describes a general direct intermolecular hydroacylation -not reported so far -of 1-alkene with aldehyde using the cocatalyst system of the transition metal complex and 2-amino-3-picoline. Some other metal complexes are also catalytically active. Without the addition of the picoline derivat