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Double bond cleavage on ultraviolet irradiation of αβ-unsaturated nitro compounds

✍ Scribed by J.T. Pinhey; E. Rizzardo

Book ID
104238443
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
116 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

Several studies of the photochemistry of o&unsaturated nitro compounds have shown that they undergo five main reactions, depending on their structural features and on the conditions used, isomerisation to the By-unsaturated compound 1,2,3 , dimerisation to give a dinitrocyclobutane4, isomerisation to an cl-oximino ketone 2,5,6 , conversion into an a& unsaturated ketone 1,2,7 1

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