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Double Asymmetric Induction in 1,3‐Dipolar Cycloaddition of Nitrones to 2,3‐Unsaturated Sugar 1,5‐Lactones

✍ Scribed by Paśniczek, Konrad; Socha, Dariusz; Jurczak, Margarita; Frelek, Jadwiga; Suszczyńska, Agata; Urbańczyk‐Lipkowska, Zofia; Chmielewski, Marek

Book ID
120381104
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
920 KB
Volume
22
Category
Article
ISSN
0732-8303

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1,3-Dipolar cycloadditions of cyclic nit
1,3-Dipolar cycloadditions of cyclic nitrones to γ-bromo α,β-unsaturated esters and lactones
✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.