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Domino Reaction of Iodoglycosides: Synthesis of Carbohydrate-Based Nitroalkenes

✍ Scribed by Soengas, Raquel G.; Silva, Artur M. S.

Book ID
120662223
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
368 KB
Volume
2013
Category
Article
ISSN
1434-193X

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The molecular mechanism of the domino reaction of nitroalkenes with silyl enol ethers to give nitroso acetal adducts was characterized using computational procedures at the PM3 semiempirical level. The domino process comprises three consecutive steps: the first and rate-determining step is the nucle