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Domino “[3 + 3]-Cyclization-Homo-Michael” Reactions of 1,3-Bissilyl Enol Ethers with 1,1-Diacylcyclopropanes.

✍ Scribed by Dopal Bose; Nguyen Van Thi Hong Nguyen Van Thi Hong; Ehsan Ullah; Sunanda Lahiri; Helmar Goerls; Peter Langer

Publisher
John Wiley and Sons
Year
2005
Weight
32 KB
Volume
36
Category
Article
ISSN
0931-7597

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[3+3] Cyclizations of 1,3-Bis(silyl enol
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Domino reactions facilitate the rapid assembly of complex products in a one-pot process. [1] Despite the simplicity of the idea, domino cyclizations of 1,3-dicarbonyl dianions [2] with dielectrophiles are relatively rare. [3] As a result of their high negative charge density, ambident dianions are v