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Does the reaction of copper(I) with hydrogen peroxide give hydroxyl radicals? A study of aromatic hydroxylation

✍ Scribed by Eberhardt, Manfred K.; Ramirez, Glenda; Ayala, Erick

Book ID
120817541
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
648 KB
Volume
54
Category
Article
ISSN
0022-3263

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The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ? 0.3) x 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experi