Does proton stability imply the existence of an extra Z0?

Experimental Evidence on the Existence o

Experimental Evidence on the Existence of an exo-π-Allyl Complex Intermediate in the Pd0-Catalyzed Alkylation of a Bicyclic Allylic Diacetate with Stabilized Nucleophiles

✍ Jean Michel Brunel; Michel Maffei; Günter Muchow; Gérard Buono 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 292 KB 👁 1 views

The Pd 0 -catalyzed alkylation of 1 by sodiodimethylmalonate led to the formation of two tricyclic diastereomers 2a and 2b. The structure of the major endo diastereomer 2b has been Scheme 1. Pd 0 -catalyzed alkylation of allylic bicyclic diacetate 1 [a] E.