Does Cr(CO) 3 Complexation Reduce the Aromaticity of Benzene?
✍ Scribed by Schleyer, Paul von Ragué; Kiran, Boggavarapu; Simion, Dan V.; Sorensen, Ted S.
- Book ID
- 120273560
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 66 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
## The reaction of Cr(CO)j-complexed chloroarenes with HCO$H:, and NaOCH3 in the presence qf a catalytic amount of PdC&PPh3)2 gives esters in good yieldr provided that the arene is substituted by an electron-&Wing group, whereas the presence of an electron-withdrawing substituent on the aromatic r
Some of the more electronegative transition metals can also be surface metallized by Zintl anions via a similar mechanism. Treatment of Pt foil with &Pb9 in en (24-48 h, 2S°C) gives lead crystals surrounded by a potassiumrich phase (XRD, SEM, EM/EDX). The potassium-rich phase is not present as K' as