Do we observe the “adiabatic” ionizations of the water dimer? An interpretation of the threshold ionization energy and the nature of the ionic states

Pulsed field threshold ionization of van

Pulsed field threshold ionization of van der Waals complexes. The dissociation energy of ionic and neutral dibenzo-p-dioxin·Ar and ·84Kr

✍ Th.L. Grebner; H.J. Neusser 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 479 KB

The technique of mass selective pulsed field threshold ionization of high long-lived Rydberg states has been applied to dibenzo-p-dioxin (DD), DD-Ar, and DD.UKr yielding adiabatic ionization energies of 61283, 61071, and 61005 cm -~, respectively. A sharp energetic threshold for the disappearance of