Do deprotonated vinylcarbinols undergo [1,3] sigmatropic rearrangements in the gas phase?
β Scribed by Peter C.H. Eichinger; John H. Bowie
- Book ID
- 103602310
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 612 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0168-1176
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
3-Chloro-2,2-dimethyIpropan-l-ol was pyrolysed in a static system at 410.0-459-1 "C and 62-179 Torr. The reaction, in a seasoned vessel and in the presence of the free radical suppressor propene, is homogeneous, unimolecular, and follows a first-order rate law. The rate coefficient follows the Arrhe