dl-Methionine dl-methioninium picrate
✍ Scribed by Anitha, K. ;Athimoolam, S. ;Rajaram, R. K.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 363 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
is composed of two crystallographically independent methionine residues and a picrate anion. The methionine and protonated methioninium residues are bonded through a strong O-HÁ Á ÁO hydrogen bond, and an inversion-related dl1 head-to-tail sequence along the a axis is observed in the zwitterion. The amino groups of two residues connect to the lone oxygen of two inversion-related picrate anions. Hydrophobic layers are observed in the y = 0 plane.
📜 SIMILAR VOLUMES
In the title compound, C 5 H 11 NO 2 S, the conformation of the terminal methyl C atom with respect to the -C atom is trans. The crystal structure is stabilized by a network of characteristic head-to-tail dl1 and dl2 sequences.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in main residue R factor = 0.058 wR factor = 0.181 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê Disorder in main residue R factor = 0.061 wR factor = 0.178 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.