DL-capacitance of solid metal electrodes compared with the liquid mercury electrode

✍ Scribed by N.A. Hampson; D. Larkin

• Publisher: Elsevier Science
• Year: 1970
• Tongue: English
• Weight: 538 KB
• Volume: 15
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(70)80009-3

✦ Synopsis

The variation of the differential capacitance at solid metal electrodes on initial electrode/ electrolyte contact are reported and interpreted in terms of an equilibration. of the equilibration processes involved are given.

Qualitative suggestions

Relationships are suggested between the "sharpness" of the differential capacitance minimum at the pzc of a solid metal and its crystal structure and also between the value of the differential capacitance for a solid metal and its melting point.

R&urn-n a rendu compte et on a interpret6 en termes d'kquilibre l'tcart de la capacittdifferentielle aux &ctrodes metalliques solides au contact initiale avec 1'Blectrolyte.

On propose qualitativement les pro&d& en jeu. On propose des relations entre la "acuit&" de la minimum de la capacitC differentielle & print de change nul d'un m&al solide et son structure cristallographique, et aussi entre la valeur de la capacitC diffkrentielle pour un m&al solide et son point de fusion.