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Division of viscosity B coefficient into ideal and net solute-solvent interaction terms for n-Hexane-n-Alkane regular solutions. Solvent and temperature effects

✍ Scribed by Tetsuo Nakagawa; Kanji Kajiwara; Soichi Hayashi


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
318 KB
Volume
75
Category
Article
ISSN
0167-7322

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✦ Synopsis


We have applied our theory of the division of the viscosity B coefficient to the n-hexane-n-heptane, -n-octane, -n-decane, -n-undecane, and -n-dodecane systems at 25°C, and to the n-hexane-n-hexadecane system at 25, 45, 65, and 85 °C. Similar to the investigation of benzene regular solutions, a linear relation holds between the Bn term and the equimolar excess enthalpy H e xa =0.5, and it has been clarified that the Bn term and the temperature coefficient of B~ for these systems are controlled by solute-solvent interaction.