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Diversity-Oriented Approach to Biologically Relevant Molecular Frameworks Starting with β-Naphthol and Using the Claisen Rearrangement and Olefin Metathesis as Key Steps

✍ Scribed by Sambasivarao Kotha; Kalyaneswar Mandal; Arti Tiwari; Shaikh M. Mobin

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 324 KB
Volume: 12
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200600540

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✦ Synopsis

Abstract

A diversity‐oriented approach for the synthesis of various structurally different molecular frameworks from readily accessible and common precursors is described. A Claisen rearrangement followed by ring‐closing metathesis or ethylene‐promoted ring‐closing enyne metathesis has been utilized as the key synthetic transformation to generate naphthoxepine derivatives. The ring‐closing metathesis approach has also been used to generate spirocyclic compounds and the pleiadene framework.

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Diversity-Oriented Approach to Biologically Relevant Molecular Frameworks Starting with β-Naphthol and Using the Claisen Rearrangement and Olefin Metathesis as Key Steps.

✍ Sambasivarao Kotha; Kalyaneswar Mandal; Arti Tiwari; Shaikh M. Mobin 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 45 KB

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