Divergence of the R−1 expansion for the second-order H–H interaction

✍ Scribed by Ralph H. Young

• Publisher: John Wiley and Sons
• Year: 1975
• Tongue: English
• Weight: 184 KB
• Volume: 9
• Category: Article
• ISSN: 0020-7608
• DOI: 10.1002/qua.560090106

✦ Synopsis

Abstract

The conventional R^−1^ expansion of the second‐order intermolecular interaction energy (R = intermolecular distance) is shown to diverge for all R in the prototype case of two 1__s__ hydrogen atoms.