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DiTOX-mediated synthesis of 2-bromo-4-deoxypyranoside derivatives

โœ Scribed by Philip C Bulman Page; Michael J McKenzie; Derek R Buckle


Book ID
104208942
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
491 KB
Volume
54
Category
Article
ISSN
0040-4020

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โœฆ Synopsis


Stereocontrolled cycloadditlon of Danishefsky's dlene to syn-Z-formyi-Zmethyi-1,3-dithlane 1-oxide is used as the basis for a short stereoselective synthesis of a 2-bromo-4-deoxymannose derivative.


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A selective synthesis of 4-bromo-2-furan
โœ Ohad Ilovich; Joseph Deutsch ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 48 KB

A selective synthesis of ethylene acetal of 4-bromo-2-furancarboxaldehyde (4) and its pinacolborane derivative (5) is described. The synthesis was carried out using 2-furancarboxaldehyde (1) that was brominated to 4,5-dibromo-2-furancarboxaldehyde (2) in an emulsion of aluminum chloride and methylen