✦ LIBER ✦
Dithiolato-Bridged [MRu2] (M = Rh, Ir, Ru) Triangular 50e– Cluster Complexes Synthesized by Complete Metal Framework Reconstruction
✍ Scribed by Norikiyo Nakagawa; Masaki Murata; Manabu Sugimoto; Hiroshi Nishihara
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 106 KB
- Volume
- 2006
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Abstract
A method for synthesizing triangular dithiolene‐bridged trinuclear cluster complexes [{LM(S~2~C~6~H~4~)}Ru~2~(CO)~4~(S~2~C~6~H~4~)] [M = Rh, L = (η^5^‐C~5~Me~5~); M = Ir, L = (η^5^‐C~5~Me~5~); M = Ru, L = (η^6^‐C~6~Me~6~)] by complete reconstruction of the metal framework was developed. The complexes thus obtained have 50 electrons around the metal atoms, indicating 3c4e^–^ bonds; their molecular structures were determined by X‐ray diffraction analyses and theoretical calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)