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Dithieno[3,4-b,3′,4′-e]-[1,4]-dithiin

✍ Scribed by Prof. Dr. M. J. Janssen; J. Bos


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
121 KB
Volume
81
Category
Article
ISSN
0044-8249

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Dithieno[3,4-b,3′,4′-e]-[1,4]-dithiine
✍ Prof. Dr. M. J. Janssen; J. Bos 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB 👁 1 views

n anes [51. As a result the intramolecular Cl.. . C1 contacts are increased to values ranging from 3.308 to 3.338 A, and the planes of the four chlorines above, and the four chlorines below the central ring are separated by 2.454 A. The bond distances give no evidence for conjugation. The distances

Ab initio molecular orbital study of ene
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Optimized geometries and energies for 3,4-dihydro-1,2-dithiin Ž . Ž . Ž . Ž . 1 , 3,6-dihydro-1,2-dithiin 2 , 4H-1,3-dithiin 3 , and 2,3-dihydro-1,4-dithiin 4 were calculated using ab initio 6-31G U and MP2r6-31G U rr6-31G U methods. At the MP2r6-31G U rr6-31G U level, the half-chair conformer of 4

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ChemInform Abstract: Bis[1,2]dithiolo[3,
✍ Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Bis [1,2]dithiolo [3,4-b][4',3'-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine. -Reaction of N-benzyldiisopropylamine (I) with S 2 Cl 2 gives N-benzyl-bisthiolothiazine (II) with typically folded structure. Debenzylation of (II) results in a dramatic flattening of the molecule structure giving th