Differentialandtotal state-to-state~sssectionsfoortheD+H,(u=O,j=O-3)~HD(u',j')+Hreactioninthe0.35-1.10eV collision energy range, have been calculated on the UTH surface using the QCT method. The results are commented on and compared to recent quantum mechanical calculations and to experimental measu
Distribution of Rovibrational Product States for the “Prompt” Reaction H + D 2 ( v = 0, j = 0−4) → HD( v ‘ = 1,2, j ‘) + D near 1.6 eV Collision Energy †
✍ Scribed by Bean, Brian D.; Fernández-Alonso, Félix; Zare, Richard N.
- Book ID
- 127260873
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 83 KB
- Volume
- 105
- Category
- Article
- ISSN
- 1089-5639
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Complete quantum state distributions for HD (u= 1) and HD(u=2) are obtained by photolyzing HI at 266 nm m the presence of D2 and detecting the nascent HD product via (2+ 1) resonance-enhanced multiphoton ionization (REMPI). Calibration against an effusive oven source ( d 1800 K) yields any necessary
The reaction H+Da+HD( u'= 1, j') t D was studied using two different experimental geometries: (1) a probe-laser-induced reaction geometry and (2) an independent-photolysis laser geometry. High-energy H atoms were generated by photolysis of HI which resulted in center-of-mass collision energies of 2.
The reaction D+ H2( v= I ) has been investigated in a crossed molecular beam experiment at the most probable collision energy of&=0.33 eV. Angular and time-of-flight distributions have been measured and the total absolute cross section has been determined to be a&, = 0, v= 1, EC ,,,. = 0.33 eV) = 1.