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Distribution of Cis-1,4 and Trans-1,4 Units in 1,4-Polyisoprene Prepared with Butyllithium in Nonpolar Solvent

✍ Scribed by Morèse-Séguéla, B.; St-Jacques, M.; Renaud, J. M.; Prud'homme, J.


Book ID
127101244
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
209 KB
Volume
10
Category
Article
ISSN
0024-9297

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Telechelic cis-1,4-oligoisoprenes throug
✍ Sandrine Gillier-Ritoit; Danièle Reyx; Irène Campistron; Albert Laguerre; Raj Pa 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 102 KB 👁 2 views

## Abstract Telechelic __cis__‐1,4‐oligoisoprenes were prepared by the selective cleavage of weak epoxidized units (E) in epoxidized __cis__‐1,4‐polyisoprenes (EPIs) and by the random cleavage of isoprenic units (I) in __cis__‐1,4‐polyisoprene (PI). In both cases, cleavage by periodic acid (H~5~IO~