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Distinct behaviour of Ti and Hf supported catalysts in the polymerization of different monoalkenes

✍ Scribed by Angelina Altomare; Roberto Solaro; Francesco Ciardelli; Lia Barazzoni; Francesco Menconi; Stefano Malquori; Francesco Masi


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
265 KB
Volume
33
Category
Article
ISSN
0032-3861

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Number of active centers and propagation
✍ Gennadii D. Bukatov; Valerii S. Goncharov; Vladimir A. Zakharov πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 409 KB

Polymerization inhibition with radioactive carbon monoxide was used to determine the number of active centers (C,) and the propagation rate constant (k,) in the isospecific polymerization of propene with the catalytic system TiCl,/diisobutyl phthalate/MgC1,-A1Et,-PhSi(OEt)3. The presence of hydrogen