Dissolving metal reduction K metal-crown ether-toluene system for reductive defluorination
✍ Scribed by Tomihiko Ohsawa; Takeshi Oishi
- Publisher
- Springer Netherlands
- Year
- 1984
- Tongue
- English
- Weight
- 516 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0923-0750
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📜 SIMILAR VOLUMES
A black-blue solution of potassium and dicyclohexyl-18-crown-6 in toluene or diglyme has been proved to be effective in the reductive cleavage of the unactivated carbon-fluorine bond. Cyclic polyethers are known to form stable complexes with various salts and,
## Abstract Structure and properties of poly(methylphenylsilane) synthesized by reductive coupling of silyl halides with alkali metal supramolecular complexes: (Mt^+^/18‐crown‐6, Mt^−^, where Mt = K, Na; 18‐crown‐6 = 1,4,7,10,13,16‐hexaoxacyclooctadecane) were investigated. The coupling process yie