𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dissolution kinetics of copper(II) oxide in water saturated by sulphur dioxide

✍ Scribed by Avni Çakici; Sabri Çolak; Zafer Eki̇nci̇; Samih Bayrakçeken


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
316 KB
Volume
26
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis


The dissolution and the kinetics of dissolution of copper(I1) oxide in water saturated by sulphur dioxide has been studied. In the experiments, the particle size, the flow rate of the gas, the solid to liquid ratio, and the reaction temperature have been chosen as parameters, while the stirring rate was held constant. As a result of present experiments, it was observed that the decrease of the particle size, the solid to liquid ratio, and an increase of the reaction temperature increased the dissolution rate. It was also observed that the flow rate of sulphur dioxide in the range of its flow rate values did not affect the dissolution rate.

The reaction kinetics of copper(I1) oxide according to the heterogeneous reaction models was examined and it was found that the dissolution rate was controlled by chemical reaction. The calculated activation energy is 66.50 kJmol-l.


📜 SIMILAR VOLUMES


The kinetics of copper dissolution in ac
✍ J. Pang; I.M. Ritchie; D.E. Giles 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 607 KB

The rate of dissolution of rotating copper discs in acidified copper(H) solutions prepared in an acetonitrile-water solvent (mole fraction acetonitrile = 0.25) was measured in the temperature range 27C-360K. The rate of dissolution was found to be proportional to the square root of the rotation spee

Kinetics and mechanism of the oxidation
✍ Evan R. Moore; Andrew E. Bourne; Todd J. Hoppe; Philip J. Abode; Steven R. Boone 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB 👁 2 views

## Abstract The mechanism by which an excess of iron(II) ion reacts with aqueous chlorine dioxide to produce iron(III) ion and chloride ion has been determined. The reaction proceeds via the formation of chlorite ion, which in turn reacts with additional iron(II) to produce the observed products. T

Kinetics of copper(II)-catalyzed oxidati
✍ Anil Kumar Sharma; Abhilasha Singh; R. K. Mehta; Sudhanshu Sharma; S. P. Bansal; 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 443 KB 👁 2 views

## Abstract To understand the chemistry of Cu(II)–NH~3~–S(IV)–O~2~ system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammonia‐buffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH~3~)^2+^, Cu(NH~3~)~2~^2+^, and C

Erratum: “Kinetics and mechanism of the
📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 88 KB 👁 2 views

## Abstract The original article to which this erratum refers was published in Int J Chem Kinet 2004, 36, 554 Because of a printing error, Fig. 7 in this paper was printed incompletely and in black and white. The correct figure appears below. We regret the error. © 2004 Wiley Periodicals, Inc. Int