Dissociative electron attachment ot NH3, NH2OH, NH2NH2 and NH2CH3
β Scribed by Talat Yalcin; Sefik Suzer
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 191 KB
- Volume
- 266
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
The geometries of the reactant, products, and transition state of the title reaction were optimized at the UHF and UMP2 levels with the double and triple zeta basis sets as well as polarization functions by using the energy-gradient method. The potential-energy barrier for this reaction is 3.73 kcal
Microwave spectra of NCCCH -NH 3 , CH 3 CCH-NH 3 , and NCCCH -OH 2 have been recorded using a pulsed-nozzle Fourier-transform microwave spectrometer. The complexes NCCCH -NH 3 and CH 3 CCH-NH 3 are found to have symmetric-top structures with the acetylenic proton hydrogen bonded to the nitrogen of t