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Dissociation pressures and enthalpies of reaction in MgCl2 · nH2O and CaCl2 · nNH3

✍ Scribed by Robert W. Carling

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
581 KB
Volume
13
Category
Article
ISSN
0021-9614

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📜 SIMILAR VOLUMES

The dissociation of NH3 and H2O in excit
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For some lower-lying excited states of NH3 and H20, ab initio SCF calculations indicate the presence of potential maxima in the paths leading to dissociation into NH2 +H and OH +H. The occurrence of these maxima is probably connected with changes in the highest occupied molecular orbital during diss

Kinetics of the reactions OH (v = O) + N
Kinetics of the reactions OH (v = O) + NH3 →; H2O + NH2 and OH(v = O) + O3 → HO2 + O2 AT 298°K
✍ Michael J. Kurylo 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 400 KB

The rate constants for the reactions OH(X 'II, kl k2 u=O) + NH3 --t HzO+ NH? and OII(X '11, u=O) + O3 -HO, + O2 were measured at 296K by the flash photolysis resonance fluorescence technique. The values of the rate constants thus obtained are kl = (4.1 +-0.6) X lo-l4 nndkz = (6.5 t 1.0) X lo-l4 in u