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Dissociation of the diphenylnitrile imine radical cation into benzonitrile and [phenylnitrene]+˙

✍ Scribed by Curt Wentrup; André Maquestiau; Robert Flammang


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
311 KB
Volume
16
Category
Article
ISSN
1076-5174

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Dissociation of the tertiary butanol rad
✍ William Beveridge; Iain W. Garioch; John A. Hunter; Chris A. F. Johnson; John E. 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 442 KB

The ionization and lowest energy unimolecular dissociation of tert-butanol were modelled by ab initio molecular orbital methods. The ion is formed on a repulsive surface and gives a methyl radical and protonated acetone as products with the liberation of 0.54 eV of energy. The calculations predict t